Showing posts with label hydroxyl. Show all posts
Showing posts with label hydroxyl. Show all posts

Friday 4 December 2015

Ocean Heat Depth

Ocean heat at the equator


On November 24, 2015, equatorial waters at ≈100 m (328 ft) depth at 110-135°W were over 6°C (10.8°F) warmer than average in 1981-2000, as illustrated by above image. The animation below shows equatorial ocean heat over the past few months, illustrating that temperature anomalies greater than 6°C (10.8°F) occurred throughout this period at depths greater than 100 m (328 ft).

The danger of ocean heat destablizing clathrates in the Arctic

The danger is that ever warmer water will reach the seafloor of the Arctic Ocean and destabilize methane that is held there in sediments the form of free gas and hydrates.

So, how comparable is the situation at the equator with the situation in the Arctic? How much heating of the Arctic Ocean has taken place over the past few years?

The image on the right, produced with NOAA data, shows mean coastal sea surface temperatures of over 10°C (50°F) in some areas in the Arctic on August 22, 2007.

In shallow waters, heat can more easily reach the bottom of the sea. In 2007, strong polynya activity caused more summertime open water in the Laptev Sea, in turn causing more vertical mixing of the water column during storms in late 2007, according to this study, and bottom water temperatures on the mid-shelf increased by more than 3°C (5.4°F) compared to the long-term mean.

This study finds that drastic sea ice shrinkage causes increase in storm activities and deepening of the wind-wave-mixing layer down to depth ~50 m (164 ft) that enhance methane release from the water column to the atmosphere. Indeed, the danger is that heat will warm up sediments under the sea, containing methane in hydrates and as free gas, causing large amounts of this methane to escape rather abruptly into the atmosphere.

The image below, replotted by Leonid Yurganov from a study by Chepurin et al, shows sea water temperature at different depths in the Barents Sea, as described in an earlier post.


The image below is from a study published in Nature on November 24, 2013, showing water temperatures measurements taken in the Laptev Sea from 1999-2012.

Water temperatures in Laptev Sea. Red triangles: summer. Blue triangles: winter. Green squares: historic data.
From Shakhova et al., (2013) doi:10.1038/ngeo2007
Before drawing conclusions, let's examine some peculiarities of the Arctic Ocean more closely, specifically some special conditions in the Arctic that could lead to greater warming than elsewhere and feedbacks that could accelerate warming even more.

Amount of methane ready for release

Sediments underneath the Arctic Ocean hold vast amounts of methane. Just one part of the Arctic Ocean alone, the East Siberian Arctic Shelf (ESAS, rectangle on map below, from the methane page), holds up to 1700 Gt of methane. A sudden release of just 3% of this amount could add over 50 Gt of methane to the atmosphere, and experts consider such an amount to be ready for release at any time (see above image).



Total methane burden in the atmosphere now is 5 Gt. The 3 Gt that has been added since the 1750s accounts for almost half of the (net) total global warming caused by people. The amount of carbon stored in hydrates globally was in 1992 estimated to be 10,000 Gt (USGS), while a more recent estimate gives a figure of 63,400 Gt (Klauda & Sandler, 2005). The ESAS alone holds up to 1700 Gt of methane in the form of methane hydrates and free gas contained in sediments, of which 50 Gt is ready for abrupt release at any time.



Imagine what kind of devastation an extra 50 Gt of methane could cause. Imagine the warming that will take place if the methane in the atmosphere was suddenly multiplied by 11.

Whiteman et al. recently calculated that such an event would cause $60 trillion in damage. By comparison, the size of the world economy in 2012 was about $70 trillion.

Shallow waters in the Arctic Ocean
Shallow waters and little hydroxyl

The danger is particularly high in the shallow seas that are so prominent in the Arctic Ocean, as illustrated by the light blue areas on the image on the right, from an earlier post.

Much of the waters in the Arctic Ocean are less than 50 m deep. Being shallow makes waters prone to warm up quickly during summer temperature peaks, allowing heat to penetrate the seabed.

This can destabilize hydrates and methane rising through shallow waters will then also enter the atmosphere more quickly, as it rises abruptly and in plumes.

Elsewhere in the world, releases from hydrates underneath the seafloor will largely be oxidized by methanotroph bacteria in the water and where methane does enter the atmosphere, it will quickly be oxidized by hydroxyl. In shallow waters, however, methane released from the seabed will quickly pass through the water column.

Large abrupt releases will also quickly deplete the oxygen in the water, making it harder for bacteria to break down the methane.

Very little hydroxyl is present in the atmosphere over the poles, as illustrated by the image on the right, showing global hydroxyl levels, from an earlier post.

In case of a large abrupt methane release from the Arctic Ocean, the little hydroxyl that is present in the atmosphere over the Arctic will therefore be quickly depleted, and the methane will hang around for much longer locally than elsewhere on Earth.

Shallow waters make the Arctic Ocean more prone to methane releases, while low hydroxyl levels make that methane that enters the atmosphere in the Arctic will contribute significantly to local warming and threaten to trigger further methane releases.

High levels of insolation in summer in the Arctic

Furthermore, the amount of solar radiation received by the Arctic at the June Solstice is higher than anywhere else on Earth, as illustrated by the image below, showing insolation on the Northern Hemisphere by month and latitude, in Watt per square meter, from an earlier post.

Warm water enters Arctic Ocean from Atlantic and Pacific Oceans

What further makes the situation in the Arctic particularly dangerous is that waters are not merely warmed up from the top down by sunlight that is especially strong over the Arctic Ocean in summer on the Northern Hemisphere, but also by warm water that flows into the Arctic Ocean from rivers and by warm water that enters the Arctic Ocean through the Bering Strait and through the North Atlantic Ocean. The latter danger is illustrated by the image below, from an earlier post.


Feedbacks

Furthermore, there are feedbacks that can rapidly accelerate warming in the Arctic, such as albedo losses due to loss of sea ice and snow cover on land, and changes to the jet stream resulting in more extreme weather. These feedbacks, described in more details at this page, are depicted in the image below.


Methane


Above image shows that methane levels on December 3, 2015, were as high as 2445 parts per billion (ppb) at 469 millibars, which corresponds to an altitude of 19,810 feet or 6,041 m.

The solid magenta-colored areas (levels over 1950 ppb) that show up over a large part of the Arctic Ocean indicate very strong methane releases.

Note there are many grey areas on above image. These are areas where no measurements could be taken, which is likely due to the strength of winds, rain, clouds and the jet stream, as also illustrated by the more recent (December 5, 2015) images on the right.

The polar jet stream on the Northern Hemisphere shows great strength, with speeds as high as 243 mph or 391 km/h (over a location over japan marked by green circle) on December 5, 2015.

So, high methane levels may well have been present in these grey areas, but didn't show up due to the weather conditions of the moment.

Furthermore, the white geometric areas are due the way the satellite takes measurements, resulting in areas that are not covered.

Finally, it should be noted that much of the methane will have been broken down in the water, before entering the atmosphere, so what shows up in the atmosphere over the Arctic is only part of the total amount of methane that is released from the seafloor.

In conclusion, the high methane levels showing up over the Arctic indicate strong methane releases from the seafloor due to warm waters destabilizing sediments that contain huge amounts of methane in the form of free gas and hydrates.

Climate Plan

As global warming continues, the risk increases that greater ocean heat will reach the Arctic Ocean and will cause methane to be released in large quantities from the Arctic Ocean seafloor. The 2015 El NiƱo has shown that a huge amounts of ocean heat can accumulate at a depth greater than 100 m (328 ft). Conditions in the Arctic and feedbacks make that methane threatens to be released there abruptly and in large quantities as warming continues.

The situation is dire and calls for comprehensive and effective action as described at the Climate Plan



On November 24, 2015, equatorial waters at ≈100 m (328 ft) depth at 110-135°W were over 6°C (10.8°F) warmer than average...
Posted by Sam Carana on Friday, December 4, 2015

Friday 30 January 2015

Why are methane levels over the Arctic Ocean high from October to March?


Water temperatures at different depth

Why are methane concentrations in the atmosphere over the Arctic Ocean so high from October through to March?

The image below, replotted by Leonid Yurganov from a study by Chepurin et al, shows sea water temperature at different depths in the Barents Sea.


Above image illustrates that, while Arctic sea water at the surface reaches its highest temperatures in the months from July to September, water at greater depth reaches its highest temperature in the months from October to March. Accordingly, huge amounts of methane are starting to get released from the Arctic Ocean's seafloor in October.

Surface temperatures in October

As the image below shows, temperature at 2 meters was below 0°C (32°F, i.e. the temperature at which water freezes) over most of the Arctic Ocean on October 26, 2014. The Arctic was over 6°F (3.34°C) warmer than average, and at places was up to 20°C (36°F) warmer than average.
  
Image from 'Ocean temperature rise'
At the same time, continents around the Arctic Ocean are frozen. Surface temperatures over the Arctic Ocean were higher than temperatures on land at the end of October, due to the enormous amounts of heat being transferred from the waters of the Arctic Ocean to the atmosphere. This was the result of ocean heat content, which in 2014 was the highest on record, especially in the Arctic Ocean, which also made that at that time of year the sea ice extent was still minimal in extent and especially in volume. 

Start of freezing period

In October, the Arctic Ocean typically freezes over, so less heat will from then on be able to escape to the atmosphere. Sealed off from the atmosphere by sea ice, greater mixing of heat in the water will occur down to the seafloor of the Arctic Ocean.

Less fresh water added to Arctic Ocean

The sea ice also seals the water of the Arctic Ocean off from precipitation, so no more fresh water will be added to the Arctic Ocean due to rain falling or snow melting on the water. In October, temperatures on land around the Arctic Ocean will have fallen below freezing point, so less fresh water will flow from glaciers and rivers into the Arctic Ocean. At that time of year, melting of sea ice has also stopped, so fresh water from melting sea ice is no longer added to the Arctic Ocean either. 

Rising salt content

As addition of fresh water ends, the salt content of the water in the Arctic Ocean starts to rise accordingly, while the Gulf Stream continues to push salty water into the Arctic Ocean. The higher salt content of the water makes it easier for ice to melt at the seafloor of the Arctic Ocean. Saltier water causes ice in cracks and passages in sediments at the seafloor of the Arctic Ocean to melt, allowing methane contained in the sediment to escape. 

Pingos and conduits. Hovland et al. (2006)
The image on the right, from a study by Hovland et al., shows that hydrates can exist at the end of conduits in the sediment, formed when methane did escape from such hydrates in the past. Heat can travel down such conduits relatively fast, warming up the hydrates and destabilizing them in the process, which can result in huge abrupt releases of methane.

Heat can penetrate cracks and conduits in the seafloor, destabilizing methane held in hydrates and in the form of free gas in the sediments.

Less hydroxyl in atmosphere

Besides heat, open water also transfers more moisture to the air. The greater presence of sea ice from October onward acts as a seal, making that less moisture will evaporate from the water. Less moisture evaporating, together with the change of seasons (i.e. less sunshine) results in lower hydroxyl levels in the atmosphere at the higher latitudes of the Northern Hemisphere, in turn resulting in less methane being broken down in the atmosphere over the Arctic.

Gulf Stream

Malcolm Light writes in this and this earlier posts that the volume transport of the Gulf Stream has increased by three times since the 1940's, due to the rising atmospheric pressure difference set up between the polluted, greenhouse gas rich air above North America and the marine Atlantic Air. 

The increasingly heated Gulf Stream with its associated high winds and energy rich weather systems then flows NE to Europe where it is increasingly pummeling Great Britain with catastrophic storms, as also described in this earlier post, which adds that faster winds means more water evaporation, and warmer air holds more water vapor, so this can result in huge rainstorms that can rapidly devastate the integrity of the ice. The image below further illustrates the danger of strong winds over the North Atlantic reaching the Arctic.


Branches of the Gulf Stream then enter the Arctic and disassociate the subsea Arctic methane hydrate seals on subsea and deep high - pressure mantle methane reservoirs below the Eurasian Basin - Laptev Sea transition. This is releasing increasing amounts of methane into the atmosphere where they contribute to anomalously high local temperatures, greater than 20°C above average.

From: The Biggest Story of 2013
Emissions from North America are - due to the Coriolis effect - moving over areas off the North American coast in the path of the Gulf Stream (see animation on the right).

The Gulf Stream reaches its maximum temperatures off the North American coast in July. It can take almost four months for this heat to travel along the Gulf Coast and reach the Arctic Ocean, i.e. water warmed up off Florida in early July may only reach waters beyond Svalbard by the end of October.

Waters close to Svalbard reached temperatures as high as 63.5°F (17.5°C) on September 1, 2014 (green circle). The image below shows sea surface temperatures only - at greater depths (say about 300 m), the Gulf Stream can push even warmer water through the Greenland Sea than temperatures at the sea surface.


Since the passage west of Svalbard is rather shallow, a lot of this very warm water comes to the surface at that spot, resulting in an anomaly of 11.9°C. The high sea surface temperatures west of Svalbard thus show that the Gulf Stream can carry very warm water (warmer than 17°C) at greater depths and is pushing this underneath the sea ice north of Svalbard.
Through to March the following year, salty and warm water (i.e. warmer than water that is present in the Arctic Ocean) will continue to be carried by the Gulf Stream into the Arctic Ocean, while the sea ice will keep the water sealed off from the atmosphere, so little heat and moisture will be able to be transferred to the atmosphere. 

Start of melting period

This situation continues until March, when the sea ice starts to retreat and more hydroxyl starts getting produced in the atmosphere. Increased sea ice melt and glaciers melt, the latter resulting in warmer water flowing into the Arctic Ocean from rivers, will cause salinity levels in the Arctic Ocean to fall, in turn causing methane levels to fall in the atmosphere over the Arctic Ocean. Furthermore, the water traveling along the Gulf Stream and arriving in the Arctic Ocean in March will be relatively cold.  


References


- Chepurin, G.A., and J.A. Carton, 2012: Sub-arctic and Arctic sea surface temperature and its relation to ocean heat content 1982-2010, J. Geophys. Res.-Oceans., 117, C06019, DOI: 10.1029/2011JC007770. http://onlinelibrary.wiley.com/doi/10.1029/2011JC007770/abstract 

- Combination image created by Sam Carana with Climate Reanalyzer, from: Temperature Rise, http://arctic-news.blogspot.com/2014/10/ocean-temperature-rise.html 

- Submarine pingoes: Indicators of shallow gas hydrates in a pockmark at Nyegga, Norwegian Sea, by Martin Hovland and Henrik Svensen (2006) http://www.sciencedirect.com/science/article/pii/S0025322705003968

- Sea surface temperature west of Svalbard,
created by Sam Carana with
http://earth.nullschool.net